glycal

Glycal is a name for cyclic enol ether derivatives of sugars having a double bond between carbon atoms 1 and 2 of the ring. The term glycal should not be ...

Glycals are unsaturated sugar derivatives in which the double bond engages the anomeric carbon atom. Such cyclic vinyl ethers are characterized by high ...

2,3不飽和醣苷可以成功地藉由烯丙基亞磷酸輔助的醣加成反應來進行合成。而Endo-Glycosyl 亞磷酸在加入催化量的氯化鋁以及各種的帶有氧的親核性試劑包括醇類及醣類可在 ...

α-GalCer是由海棉中的天然物加以衍生而來的分子，早期發現其具有抗癌活性。在後來的研究中指出α-GalCer可以與CD1d結合，藉由T細胞受器刺激NKT細胞，進而釋放出會產生TH1或TH2 ...

A glycal is a type of alkaloid found in plants, such as Momordica charantia, that has been shown to have anti-diabetic properties. Specifically, the glycal ...

Glycal is a very versatile synthetic intermediate, especially in the synthesis of 2-deoxyglycosides. A thorough and useful review of the general glycal ...

References · 1)Review · 2)Synthesis of 2-deoxy-α-glycosides · 3)Synthesis of 2-deoxy-β-glycosides · 4)Synthesis of 2-azido-2-deoxyglycosides.